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Self-regulation is crucial for student success in scientific inquiry and engineering design. However, it remains unclear how students dynamically engage in self-regulated learning (SRL) processes to achieve high performance. In this study, we investigated the temporal nature of self-regulation during engineering design by leveraging computer trace data from 101 high school students who designed an energy-plus house in a simulated learning environment. Using sequential mining, we found that high-performing students were more engaged in the Observation, Analysis, and Evaluation phases of SRL than low-performing students. Additionally, high-performing students demonstrated consecutive sequential patterns between Observation and Analysis, Reformation and Evaluation, and Analysis and Evaluation behaviors. These findings provide insights into students’ SRL processes and the design of scaffoldings. 

Abstract This study explores the Antarctic sea ice concentration (SIC) response to multiyear (MY) and single-year (SY) El Niños using a 2200-yr CESM1 preindustrial simulation. During the first austral winter, MY El Niño weakens the amplitude of the typical SIC anomaly pattern induced by SY El Niño but maintains the same impact pattern. During the second winter, MY El Niños not only intensify the amplitude but also shift the typical impact pattern of SY El Niños eastward. The amplitude variation effect on SIC is caused by an Indian Ocean memory mechanism, while the zonal shifting effect on SIC pattern is caused by an Atlantic Ocean memory mechanism. These mechanisms result from the different responses of the two oceans to different locations and intensities between SY and MY El Niños. Observed MY El Niños during 1979–2020 confirm the distinct impacts during the second austral winter revealed by the CESM1 simulation. These results demonstrate that SIC in the Ross and Amundsen–Bellingshausen–Weddell Seas is sensitive to the SY or MY types of El Niño. 

Abstract Twisted moiré photonic crystal is an optical analog of twisted graphene or twisted transition metal dichalcogenide bilayers. In this paper, we report the fabrication of twisted moiré photonic crystals and randomized moiré photonic crystals and their use in enhanced extraction of light in light-emitting diodes (LEDs). Fractional diffraction orders from randomized moiré photonic crystals are more uniform than those from moiré photonic crystals. Extraction efficiencies of 76.5%, 77.8% and 79.5% into glass substrate are predicted in simulations of LED patterned with twisted moiré photonic crystals, defect-containing photonic crystals and random moiré photonic crystals, respectively, at 584 nm. Extraction efficiencies of optically pumped LEDs with 2D perovskite (BA)₂(MA)_n−1Pb_nI_3n+1ofn= 3 and (5-(2′-pyridyl)-tetrazolato)(3-CF₃−5-(2′-pyridyl)pyrazolato) platinum(II) (PtD) have been measured. 

Described herein are the synthesis, structure, and photophysics of the iodo-substituted cyclic trinuclear copper( i ) complex, Cu 3 [4-I-3,5-(CF 3 ) 2 Pz] 3 supported by a highly-fluorinated pyrazolate in comparison with its previously reported 4-Br/4-Cl analogues. The crystal structure is stabilised by multiple supramolecular interactions of Cu 3 ⋯I and hydrogen/halogen bonding. The photophysical properties and supramolecular interactions are investigated experimentally/computationally for all three 4-halo complexes vis-à-vis relativistic effects. 

Research on self-regulated learning (SRL) in engineering design is growing. While SRL is an effective way of learning, however, not all learners can regulate themselves successfully. There is a lack of research regarding how student characteristics, such as science knowledge and design knowledge, interact with SRL. Adapting the SRL theory in the field of engineering design, this study proposes a research model to examine the mediation and causal relationships among science knowledge, design knowledge, and SRL activities (i.e. observation, formulation, reformulation, analysis, evaluation). Partial least squares modeling was utilized to examine how the science and design knowledge of 108 ninth-grade participants interacted with their SRL activities in the process of performing an engineering task. Results reveal that prior science and design knowledge positively predict SRL activities. They also show that reformulation and analysis are the two SRL activities that can lead to an improvement in post science and design knowledge, but excessive observation can hinder post design knowledge. These results have important implications for the construction of learning environments to support SRL based on students’ prior knowledge levels. 

Described herein is the synthesis and photophysics of two tetranuclear copper complexes, {[3,5-(Pr i ) 2 ,4-(Br)Pz]Cu} 4 and {[3-(CF 3 ),5-(Bu t )Pz]Cu} 4 tailor-designed by manipulating the pyrazolyl ring substituents. Unlike their trinuclear analogues, the luminescence of the tetranuclear species is molecular (not supramolecular) in nature with extremely high solid-state quantum yields of ∼80% at room temperature.